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Date: Tue, 23 Jul 91 12:03 EST
Back by popular demand this post comprises the bulk of knowledge I have obtained
in the last day of study on methods of ice-core dating.
Outline
I. Methods of Dating Ice Cores
A. Counting of Annual Layers
1. Temperature Dependent
2. Irradiation Dependent
B. Using Pre-Determined Ages as Markers
1. Previously Measured Ice-Cores
2. Oceanic Cores
3. Volcanic Eruptions
4. Ph Balances
5. Paleoclimatic Comparison
C. Radioactive Dating of Gaseous Inclusions
D. Ice Flow Calculations
II. The Vostok Ice-Core
A. How It Was Collected
B. Experimental Methodology
C. Results
III. Conclusions
A. Minimum Age of the Earth
B. Worlds in Collision?
IV. References
A. Method of Collecting
B. References
------------------------------------------------------------------------------
I. Methods of Dating Ice Cores
Of the four distinct methods for determining the ages of ice cores, the first
three are direct experimental tests and the fourth rests on somewhat uncertain
theories. The accuracy of such age determinations is within 2-3 years back to
8,000 BP (before present), increasing to 2%-3% back to 20,000 BP, and
increasing to ~10% back to ~150,000 BP.
I.A. Counting of Annual Layers
The basis of this method lies with looking for items that vary with the
seasons in a consistent manner. Of these are items that depend on the
temperature (colder in the winter and warmer in the summer) and solar irradience
(less irradience in winter and more in summer). Once such markers of seasonal
variations are found, they can be used to find the number of years that the
ice-core accumulated over. This process is analagous to the counting of tree
rings. A major disadvantage of these types of dating is that they are
extremely time consuming.
I.A.1. Temperature Dependent
Of the temperature dependent markers the most important is the ratio of 18O
to 16O. The water molecules composed of H2(18O) evaporate less rapidly and
condense more readily then water molecules composed of H2(16O). Thus,
water evaporating from the ocean it starts off H2(18O) poor. As the water vapor
travels towards the poles it becomes increasingly poorer in H2(18O) since the
heavier molecules tend to precipitate out first. This depletion is a
temperature dependent process so in winter the precipitation is more enriched
in H2(16O) than is the case in the summer. Thus each annual layer starts 18O
poor becomes 18O rich and then ends up 18O poor again.
This process also depends on the relative temperatures of different years,
which allows comparison with paleoclimatic data (see I.B.5). For similar
reasons the ratio of deuterium to hydrogen (in the H2 part of water) acts the
same way.
The major disadvantage of this dating method is that isotopes tend to diffuse
as time proceeds.
I.A.2 Irradiation Dependent Markers
Of the irradiation dependent markers the two most important are 10Be and
36Cl. Both of these isotopes are produced by cosmic rays and solar irradiation
impinging on the upper atmosphere, and both are quickly washed from the
atmosphere by precipitation. By comparing the ratios of these isotopes to their
nonradioactive counterparts (i.e. 9Be and 35Cl) one can determine the season of
the year the precipitation occurred. Thus each annual layer starts 10Be and
36Cl poor, becomes 10Be and 36Cl rich, and then becomes poor again.
The major disadvantage of this dating method is that these isotopes also tend
to diffuse over time.
I.B. Using Predetermined Ages as markers
In these methods, one uses the age of previously determined markers to
determine the age of various points in the ice-core. The major advantage of
these methods is that they can be completed relatively quickly. The major
disadvantage is that if the predetermined age markers are incorrect than the age
assigned to the ice-core will also be incorrect.
I.B.1. Peviously Measured Ice-Cores
In this method one compares certain inclusions in a ice-core whose age has
been determined with a seperate method to similar inclusions in an ice-core of
a still undetermined age. These inclusions are typically ash from volcanic
eruptions (see I.B.3) and acidic layers.
The major disadvantage of this method is that one must have a previously
age-dated ice-core to start with.
I.B.2. Oceanic Cores
In this method one compares certain inclusions in dated ocean cores with
related inclusions found in the ice-core of a still undetermined age. Examples
of such inclusions are a decrease (or increase) in temperature over a period of
years that can be determined from flora and fauna found in the oceanic core and
a decrease (increase) in the 18O enrichment over this same period of years.
Another example is volcanic ash.
The major disadvantages of this method are that one must compare different
signatures of climatic change that correspond to the same event and that one is
not certain of the lag times (if any) between oceanic reactions and glacial
reactions to the same climatic changes
I.B.3. Volcanic Eruptions
After the eruption of volcanoes, the volcanic ash and chemicals are washed
out of the atmosphere by precipitation. These eruptions leave a distinct marker
within the snow from which washed the atmosphere. We can then use recorded
volcanic eruptions to calibrate the age of the ice-core. Since volcanic ash is
a common atmospheric constituent after an eruption, this is a nice signature to
use in comparing calibrated time data and an ice-core of undetermined age.
Another signature of volcanism is acidity.
The major diasadvantage of this method is that one must previously know the
date of the eruption which is usually not the case. Furthermore the alkaline
precipitants of the ice ages (I.B.4) limits this measure to approximately 8000
BP (Before Present).
I.B.4. Ph Balances
One unique marker of periods of glaciation is that precipitation during the
ice ages are markedly alkaline. This is due to the fact that the ice ages tied
up a large quantity of the available water thus exposing a larger portion of
the continental shelves. From these shelves huge clouds of alkaline dusts
(primarily CaCO3) were blown across the landscape.
The major disadvantage of this method is that it gives only very approximate
age ranges (i.e. this ice was laid down during the ice age). Furthermore, the
lag time between the onset of glaciation and increased alkalinity are uncertain.
I.B.5 Paleoclimatic Comparisons
In this method, one compares long range climatic changes (e.g. ice ages and
interglacial warmings) with markers (such as the 18O/16O ratios) found within
the ice-cores.
The major disadvantage of this method is that one must understand major
paleoclimatic changes to have something to compare to.
I.C. Radioactive Dating of Gaseous Inclusions.
In this method one melts a quantity of glacial material from a given depth,
collects the gases that were trapped inside and use standard 14C and 36Cl
dating.
The major disadvantage of this method is that a huge amount of ice must be
melted to gather the requisite quantity of gases.
I.D. Ice Flow Calculations
In this method, one measures the length of the ice core and calculates how
many years it must have taken for a glacier of that thickness to form.
This is the most inaccurate of the methods used for dating ice-cores. First
one must calculate how the thickness of the annual layer changes with depth.
After this one must make some assumptions of the original thickness of the
annual layer to be dated (i.e. the amount of precipitation that fell on the
area in a year).
II. The Vostok Ice-Core
To demonstrate the methods used in dating ice-cores I will use the Vostok
ice-core as an example because I found plenty of literature on it and because it
is an Antarctic ice-core which was what the original post was about.
II.A How It Was Collected
The Vostok Ice-Core was collected in East Antarctica by the Russian Antarctic
expedition. The Vostok Ice-Core is 2,083 meters long and was collected in two
portions: 1) 0 - 950 m in 1970-1974, 2) 950 - 2083 m in 1982-1983. The total
depth of the ice sheet from which the core was collected is ~ 3,700 meters.
II.B. Experimental Methodology
The ice core was sliced into 1.5-2.0 meter segments. A discontinuous series
sampled every 25 meters and a continuous series from 1,406 to 2,803 meters were
then sent in solid form to Grenoble, France for further analysis.
At Grenoble the ice was put into clean stainless steel containers. The
samples were crushed and then melted with the gases given off collected and
saved for further analysis. The melt water was tested for chemical composition
and a quantity of this water was then electrolysised.
The methods used in the determination of the ages include 18O/16O isotopic
analysis [1], independent ice-flow calculations [1], comparison with other ice
cores [1], paleoclimatic comparison [1], comparison with deep sea cores [1],
10Be/9Be isotopic analysis [2], deuterium/hydrogen isotopic analysis [3],
comparison with marine climatic record [3], CO2 correspondances between dated
ice-cores [4] and CO2 correspondances with dated oceanic cores [4].
The results determined from these various samples were consistent between the
continuous and discontinuous slices within the sections that overlapped. They
were also consistent with Greenland ice-cores, other Antarctic ice-cores, dated
volcanic records, deep sea cores, and paleoclimatic evidence.
II.C. Results
While unable to provide specific dates (within a millenia), the analysis show
definate evidence of the the last two ice ages. Using the methods listed above
the bottom of the ice-core was laid down 160,000 +- 15,000 years ago. It should
be noted that all of the methods listed above were consistent with the above
results.
III. Conclusions
In this section I will provide a brief review of how the ice-core data
effects both the age of the earth question and the Velikovskian catastrophism.
III.A. Minimum Age of the Earth
From the data gathered from the Vostok ice-core indicates that the MINIMUM
age of the earth is at least 145,000 years. Furthermore there exists ~ 33%
of additional ice below the core sample which would hold a disproportionate
number of years due to thinning of the ice layers under the tremendous pressure
of the ice above it.
To maintain an age for the earth of 50,000 years, one would need to
describe a mechanism that allows more than 2 false ice layers to form per year.
It should be noted that one also needs to describe why this mechanism has ceased
to function in historic times since the Vostok ice-core demonstrates a number of
the historically recorded volcanism at the correct periods of time.
III.B. Worlds in Collision
The Vostok ice-core shows no effects of catastrophic geological changes. By
this I mean no petroleum, no vermin, no weird Venus gasses, no red snow, no
manna in amongst the layers. Also no evidence for rapid rotational changes in
the earth, no floods, no major asteroid bombardments. Finally, there is
absolutely positively fur-darn-tootin no evidence of the earth ever having
occupied any position in the solar system other than that which it holds now.
IV. References
A brief note on the references I used.
IV.A. Methods of Collecting
When I went to look for references on the dating of ice-cores, I decided to
follow a simple philosophy...as simple as scientifically possible. I chose to
do this to demonstrate that there is no excuse for someone to make the blatantly
ignorant attack that Ted made when answering Sue Bishop's original post on
ice-core data.
The above sections on the Vostok ice-core was taken from references 1-4.
The general information on dating methods comes from references 5-8. The last
two references are about Greenland ice-cores.
IV.B. References
[1] C. Lorius et al., NATURE 316 (1985) 591-596.
[2] F. Yiou et al., NATURE 316 (1985) 616-617.
[3] J. Jouzel et al., NATURE 329 (1987) 403-408.
[4] J.M. Barnola et al., NATURE 329 (1987) 408-414.
[5] van Nostrands' SCIENTIFIC DICTIONARY
[6] THE ENCYCLOPEDIA OF SCIENCE AND TECHNOLOGY
[7] E. Wolff, GEOGRAPHICAL MAGAZINE 59 (1987) 73-77.
[8] Julie M. Palais OCEANUS 29 (Winter 86/87) 55-60.
[9] W. Dansgaard et al., SCIENCE 218 (1982) 1273-1277.
[10] C.U. Hammer et al., NATURE 288 (1980) 230-235.
From SBISHOP@DESIRE.WRIGHT.EDU Tue Jul 23 09:03:24 1991
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From: SBISHOP@DESIRE.WRIGHT.EDU
To: sbradley
Subject: Re: Request For Some Information From Past Posts
Date: Tue, 23 Jul 91 12:03 EST
Matt Brinkman writes:
\Been doing a little more reading on the ice-core dating techniques. I found
\something that should have been included in my original post...
\The accuracy of ice-core dating techniques is within 1-2 years back 8,000 BP
\(before present), within 2%-3% back to 20,000 BP and increasing to ~10% for
\dates ranging back to ~150,000 BP.
\If I lead anyone to believe that the methods were 100% precise, I apologize.
I want to complement Matt on his extremely well written and concise
explanation of ice core dating. Once again there is no response from
either Bob or Ted.....
--------------------------------------------------------------------------------
Matt Brinkman
Sue
From SBISHOP@DESIRE.WRIGHT.EDU Tue Jul 23 09:04:44 1991
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From: SBISHOP@DESIRE.WRIGHT.EDU
To: sbradley
Subject: Re: Request For Some Information From Past Posts
Date: Tue, 23 Jul 91 12:04 EST
I have asked this question of Bob Bales with no answer. I am asking it of Ted
Holden. Why am I fairly sure he won't answer either? Ted, you keep talking
about a world wide flood. Where did all that water come from? Even if the
polar icecaps melt there would only be a rise of sea level of about a hundred
or so feet. I'm going to be generous and give you some latitude. Say the
flood only flooded to the depths of the Rockies, i.e. 14,000 feet. I could be
tough and say the depth of Mount Everest which would satisfy the Bibical
account but I AM being generous. Calculate the volume of the earth as it is
now. Then add a total extra depth of 14,000 feet. This would increase the
diameter of the earth a total of 28,000 feet. Calculate how much is the volume
of the encreased globe. Then subtract the original volume. Compare it to the
actual volume of the oceans. I'm sure that some source book in the library can
give you this number. Any good reference librarian should be able to find it
for you.
Then come back and explain to me where all that extra water came from. I'm
sick of creationists and catastrophists coming up with crazy theories and not
even trying to work out the numbers to see if it is feasible.
I am asking you to put up or shut up.
From SBISHOP@DESIRE.WRIGHT.EDU Tue Jul 23 09:04:49 1991
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From: SBISHOP@DESIRE.WRIGHT.EDU
To: sbradley
Subject: Re: Request For Some Information From Past Posts
Date: Tue, 23 Jul 91 12:04 EST
I am reposting this information since it is germaine to the discussion
regarding the Bibical Flood. Please note the ENORMOUS volume difference
between actual water on earth and the amount needed for even enough to
cover Mount Ararat.
My thanks to Steven Timm who wrote this.
Sue Bishop
Date: Mon, 2 Jul 90 23:53:54 EDT
From: TIMM@FNAL.Bitnet
It was suggested a while ago that someone calculate the amount of water
required for a global flood which would cover the highest mountains.
Most probably the poster knew (as I do) that this calculation is already
done in Strahler. But since I don't have Strahler with me, I'm doing
the calculation for myself. After I answer the question, I'll go
on to calculate the first-order objections to the calculations that
creationists including myself would otherwise raise.
X-Envelope-to: ST0O@ANDREW.CMU.EDU
AMOUNT OF WATER ON THE EARTH TODAY: (EB is Encyclopedia Britannica)
Ocean volume: (EB 25:125) 1.37 E09 km^3.
Ice cap volume: EB 1:440
3 E08 km^3 of Antarctic ice. Antarctic ice is 90% of all ice, and ice is
..9 the density of water (can be denser under high pressure, but I believe
it's a second order effect.)
Thus 1.67E09 km^3 of water is available to make a flood.
Why no more? Water is massive enough so that it won't make escape velocity,
unless pushed to high temperatures. (RMS vel 100 C is 700 m/s, esc. vel
is 7000 and some. Thus whatever water was here still is here.
AMOUNT OF WATER TO COVER EARTH UNIFORMLY TO A DEPTH r.
With earth of radius R=1.2 E 7 m, the volume of water to cover
a perfect sphere to depth r above its surface is
4/3 pi *( 3 r * R^2 + 3R* r^2 + r^3). For the cases I will consider,
R>>r and only the first term is important.
Cover Mt. Everest: (8900 m) 1.6 E10 km^3 of water needed. If oceans
were present depth, add an additional 1.37E09.
A first-order correction is that we must consider the volume of land
mass above sea level. But it's clear there's not enough water
to go around.
The first Creationist objection would be: How do you know Everest was
that high during the flood?
All right. Let's take Mt. Ararat (3900 m) which the Bible says the
ark landed *on the top of*. For waters that high, 2.78E09 km^3 of
extra water is needed.
If all this came from forty days and forty nights of rain, this would
mean a flow of 821 km^3 per second. Whether from "fountains of the deep
or from above, the average precipitation would be 1.1 mm /sec or
~6 cm/minute (assuming uniform depth build-up to 3900 m over the
40 days, not quite correct)
>From here on creationists must play with the initial conditions.
In particular, if someone suggests that all continental drift
and most mountain formation happened during the flood, and perhaps
the ocean wasn't as deep then as it was now, let's calculate
how shallow the ocean would have to be.
Take ocean surface area 3.6E8 km^2, mean depth 3.8 km. (now).
Reduce ocean depth to 1 km, say.
Now only 3.6E8 km^3 of water is needed to fill ocean, rest
(1.2E9), is available for flood, enough to flood earth uniformly
to a depth of 2.7 km.
I won't claim that the above scenario happened. Some will, or
variations on a theme of that. Point is, where they are free
to use the Bible to pick their initial conditions, they can
come up with volumes of water that are at least on the right
order of magnitude. So there's the science and speculation.
Take it for what it's worth.
Share and enjoy,
Steve
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