[] TL: GREENPEACE STUDY: THE ELBE SO: Greenpeace Germany (GP) DT: Spring 1990 Keywords: toxics rivers germany elbe europe greenpeace gp reports / Results of the Measuring and Campaign Trip of the Beluga in the Spring of 1990 Scientific revising and editing: OKOPOL - Institute of ecology and Politics GmbH, Hamburg (Abridged Version) CONTENTS Foreword by the publishers Preface by the authors The drainage area of the Elbe The sections of the Elbe The Elbe and conservation Stations of the Beluga VEB Vereinigte Zellstoffwerke Pirna (Pirna State-Owned Pulp Works) VEB Pharmazeutisches Kombinat GERMED, Dresden (GERM ED State-Owned Pharmaceutical Combine) Zellstoffwerk Coswig (Coswig Pulp Mill) VEB Chemiewerk Nunchritz (Nunchritz State-Owned Chemicals Plant) Black Elster VEB Synthesewerk Schwarzheide (Schwarzheide State-Owned Synthesis Plant) VEB Kombinat Agrochemie Piesteritz (Piesteritz State-Owned Agrochemicals Combine) The Mulde VEB Chemiekombinat Bitterfeld (Bitterfeld State-Owned Chemicals Combine) VEB Fotochemisches Kombinat Wolfen (Wolfen State-Owned Photochemicals Combine) The Saale Low temperature carbonization of brown coal VEB Chemische Werke Buna (Buna State-Owned Chemicals Works) VEB Leuna-Werke "Walter Ulbricht" (Walter Ulbricht State-Owned Works in Leuna) VEB Fahlberg-List VEB GroBgaserei Magdeburg (State-Owned Gasworks in Magdeburg) VEB Zellstoffwerke Wittenberge (State-Owned Pulp Works in Wittenberge) Hamburgs contribution to pollution of the Elbe Dow Stade BmbH Temming AG, Gluckstadt Bayer AG, Brunsbuttel Drinking water Evaluation and conclusions References Lexicon of hazardous substances The ship's laboratory Foreword by the publishers The opening of the East has brought with it new opportunities and challenges for the former GDR. Carefully guarded secrets about pollution and destruction of the environment in this part of Europe were revealed and it became clear just how urgently an environmental policy is needed that is geared to the future and avoids past mistakes. For the first time environmental groups were able to state their demands and expectations openly and actively engage in politics. For the international environmental organization, Greenpeace, the days of illegal activities in the GDR came to an end as well. In the spring of 1990 it was possible to found a section in the GDR (Greenpeace e.V. GDR). At the same time it became clear that quick action was called for. In the course of considering a plan of action the Elbe river became a prime focus of Greenpeace's work for a number of reasons. - The catastrophic condition of the river had proven once again that international environmental problems require intense cooperation among all countries. Past discussions on the correct borderline along the Elbe, which now seem ridiculous, were a major hindrance to its clean-up. - Most of the population of the former GDR live in the drainage area of the Elbe and are directly dependent on the river's water. In addition, the industrial centers with their widely varying impacts on the environment are also located here. The Elbe will be a useful indicator of any improvement in the environmental situation in the five new German states. - Immense pollutant loads are discharged daily into the North Sea by the Elbe. Greenpeace has been fighting for years to save this ecosystem, which has already received some irreversible damage. Consequently, it was a logical step to also extend activities to one of the major inflows. - To save the river, fundamental political decisions must be demanded with massive public backing. Rebuilding the industry in the five new German states offers a unique historical opportunity to put into practice a model for dealing with nature that is ecologically responsible and socially compatible. The Elbe could thus become the model for a fundamental ecological reorientation of industrial society in the East and West. It is hoped that the ecological-political evaluation of the Greenpeace Elbe trip presented here will make a constructive contribution to the decision-making process. Jorg Naumann, Christoph Thies G r e e n p e a c e November 1990 If not otherwise specified, the analyses on which this study is based were carried out by: AL control GmbH - independent laboratory specializing in the environment, Bremen. Foreword by the Authors From April to May 1990 the Greenpeace measuring and campaign ship, the Beluga, travelled the Elbe, measuring pollutants, informing the population and conducting campaigns at the worst polluters of the Elbe. The aim was to draw attention to the extent of pollution of this river as well as to economic consequences and possible corrective actions. The present report was originally meant to be purely a travel log of this trip but its character has since gradually changed. As the GDR disbanded, the states joined the Federal Republic of Germany, nationally- owned businesses were converted to capitalist forms of business, and plants were modified or shut down, there were also so many changes at the plants and combines visited by Greenpeace that just a few weeks after the trip it seemed senseless to publish a mere travel log describing facts as found and uncovered by Greenpeace. Documentation of the old condition is still important but it is no longer adequate. Even now it is still daring to publish the present study, as developments continue to progress rapidly and many are not nearly complete. Just one example is the ghost of I.G Farben. It was long believed to be dead but has recently reared its head and filed claims for the possession of Buna, Leuna, Wolfen, Bitterfeld and Piersteritz plants also treated in this report. This report does not pretend to be complete. This applies not only to documentation of the condition of the Elbe and its drainage area, which encompasses virtually all of the GDR, as it was at the beginning of this year. This is even more applicable to the description of current developments and future plans for redeveloping the GDR economy. The amount of information available for different plants and combines varies considerably as it depends largely on the willingness on the part of those responsible in plants and the authorities to provide this information. Often the public was not sufficiently aware of the fact the Beluga made stops not only in the GDR but also in the FRG to point out environmental destruction there as well. These stops, which received too little attention in mass media reports, will be evaluated once again in detail in the present report. The main idea is to communicate the mistakes made in the West, whether in establishing businesses, in poor planning in the use and exploitation of the land and resources or in setting up inadequate standards, to the people and politicians of the new states of the FRG in such a way that they will not repeat painful mistakes. Finally, the report will try to show just how far the industries in the West are removed from a production that is beneficial to the environment and man and to define goals that will be worth pursuing even in years to come. Sabine Winteler, Joachim Lohse Okopol, November 1990 Stations of the Beluga in the GDR and FRG The Greenpeace campaign ship, the Beluga, travelled the Elbe from Czechslovakian border to the mouth of the river from April 7, 1990 to May 10, 1990. The purpose of the trip was to make use of the political opening of the former GDR to point out flagrant destruction of the environment, to gather and disseminate information and, whenever possible, to remedy deplorable situations quickly. At the same time the Beluga trip was supposed to establish a connection to the production processes on the former territory of the FRG. Although direct contamination of water, air and soil from them is not as high, sludge, flue dust, slag, toxic waste and ultimately the marketed finished products (eg made of PVC) themselves create many environmental problems. The trip focused primarily on problems relating to chlorinated hydrocarbons with their innumerable adverse effects on the environment and all levels of living organisms including man. These hazardous substances are discharged into the Elbe mainly from the sewage pipes of the chemicals industry and by pulp industry plants that still use chlorine bleaching. Campaigns were conducted at the Arzneimittelwerk Dresden (pharmaceutical production), at the Fotochemischen Kombinat Wolfen (photochemicals), the pesticide manufacturer, Fahlberg- List, the important West German chemicals producers, Dow Stade and Bayer Brunsbuttel as well as at the pulp production facilities in Pirna, Coswig, Wittenberge and Gluckstadt. However, Greenpeace's work was not limited to campaigns alone. Numerous talks were also held with those in responsible positions. Moreover, at several locations water samples from the Elbe and its most important tributaries were analysed. Detailed summary of the results: VEB Vereinigte Zellstoffwerke Pirna: (Pirna State-Owned Pulp Works) The pulp mill in Pirna is located on the left bank of the Elbe between the Czechoslovakian border and Dresden and produces sulfite wood pulp from beech wood for the manufacture of synthetic fibers. During the production process the wood pulp is bleached with chlorine chemicals. The production of wood pulp loads waste waters with dissolved and suspended wood constituents that generate a high oxygen demand detectable as the chemical oxygen demand COD. Bleaching loads waste waters with the products of lignin chlorination that are virtually non-biodegradable and can be toxic. Greenpeace measurements gave an AOX (a measure of the load of organochlorine compounds) of 30,000 micrograms and a COD of more than 1,000 milligrams per liter. The explosive nature of this toxic load in the waste water is enhanced by the fact that drinking water is obtained from the riverside filtrate of the Elbe. Just a few kilometers below the Pirna plant the Hosterwitz and Tolkewitz water works are located on the right and left banks of the Elbe respectively. With 2,4,5-trichlorophenol the Beluga's laboratory was able to track down a hazardous toxic substance in the Tolkewitz water works that had previously been identified in the waste water of the bleaching plant in Pirna but not in the Elbe above Pirna. The mill's management attempted to play down the measured load by arguing that only 0.6 per cent was actually toxic. However, it is a known fact that decomposition processes taking place in water can break down the large, initially "harmless" molecules into smaller fragments that can very easily be toxic. Prospects A pulp liquor concentration facility and a biological sewage treatment plant will not go into operation until the end of 1993. Until then the Elbe will continue to be loaded with 300 tons of COD daily, the highest organic pollutant load from any of the pulp works in the former GDR. The decision of Summer 1990 to stop bleaching with pure chlorine does not go far enough. Only a total ban on all chlorine- containing chemicals, ie chlorine dioxide and hypochlorite as well, can reduce the AOX to zero. A totally chlorine-free viscose fiber is now already on the market. This refutes the argument so often used that it is impossible to produce pulp for synthetic fiber production without chlorine bleaching. VEB Pharmazeutisches Kombinat GERMED, Dresden (GERMED State-Owned Pharmaceutical Combine) The largest drug manufacturer in the territory of the former GDR with a total of 3500 employees produces about 250 chemical- pharmaceutical products, such as cardiovascular drugs, psychotropic drugs and antirheumatic agents. The plant pollutes the air with soot from the brown coal power plant and a wide variety of harmful substances emitted from approximately 400 chimneys and fume hoods. The grounds are most likely highly contaminated owing to several burst sewage pipes and must be considered one big abandoned pollution area. The only measure taken to control waste water until the spring of 1990 consisted of a stacking container for "equalization", ie for compensating extreme fluctuations in the acid content. In the Greenpeace water samples high concentrations of oxygen- depleting substances and organochlorine compounds were found including, for example, the highest concentration of hexachlorobenzene of the whole trip as well as PAH's, toluene, chlorinated solvents, chlorobenzenes and chlorophenols. Management at first denied several effluents, as for example the solvent carbon tetrachloride. However, it turned out that unknown to the plant management carbon tetrachloride was still being used in the apprentices' workshop. Greenpeace's greatest achievement was to force the plant to take a close look at each of its own processes individually in an effort to eliminate unnecessary emissions. In addition, the Water Conservation Authority ordered a stop to parts of production and issued a ban on the discharge of the pollutants in the highest water hazard category, carbon tetrachloride, chloroform and benzene. Standards limiting the emission of other hazardous substances were also established. In September 1990 the COD load in the waste water was in fact reduced by 50 per cent. Chloroform, carbon tetrachloride and benzene are avowedly no longer being discharged. Plans for more far-reaching measures, such as incineration of toxic wastes or joint treatment of the plant waste water with the municipal sewage of Dresden must be viewed with a great deal of skepticism. VEB Chemiewerk Nunchritz (Nunschritz State-Owned Chemical Works) This plant near Riesa has about 2000 employees. It produces sulfuric acid and its secondary products, silicone products for adhesives, paints, rubber and oils and even two "ozone killers", the chlorofluorocarbons, CFC-11 and CFC-12. In addition, the silicone-based building conservation agent, "Contraquin", and teflon are produced. Silicone production was begun in the early 60's. The plant discharges approximately 4,000 cubic meters of highly contaminated waste water into the Elbe daily. Particularly hazardous pollutants include chlorobenzenes, chlorophenols, chlorinated solvents (eg carbon tetrachloride) and heavy metals (especially copper). The Beluga laboratory once again proved to be an excellent detective when finding the right places to take samples, as the sensors for measuring the temperature and oxygen content were covered with a sticky, viscous mass. This was raw uncrosslinked silicone that was obviously contained in considerable concentrations in the waste water of the Nunchritz Chemical Works. A talk with plant management revealed that neutralization was the only waste water treatment on the premises. The plant management had no explanation for the source of the solvent (chloroform) and chlorinated benzenes. Prospects Continued production of ozone-depleting CFC's is totally unacceptable. Production must be stopped immediately!!! (At the same time this would solve the problem of carbon tetrachloride emissions.) It should be relatively easy to separate the other pollutants from the waste water. Heavy metals and organic pollutants can often be recycled and do not have to end up either as water pollutants or as waste. In the medium- and long- term, an ecologically safe reorganization of the plant production should focus on phasing out substances with questionable properties. Black Elster Although the confluence of the Black Elster improves the level of nutrients in the Elbe, it also pollutes the Elbe with cyanide, oxygen-depleting substances and organochlorine compounds. Some of those responsible for this include the Synthesewerk Schwarzheide (Schwarzheide Synthesis Plant), Zellstoffwerk Groditz (pulp mill) and the Lauchhammer brown coal refinery. VEB Kombinat Agrochemie Piesteritz (Piesteritz State-Owned Agrochemicals Combine) The VEB Kombinat Agrochemie Piesteritz is located on the right bank of the Elbe in Wittenberg-Piesteritz. It produces in addition to inorganic acids (sulfuric acid, nitric acid, phosphoric acid) a wide variety of nitrogen- and phosphorus based fertilizers, eg urea, calcium cyanamide, and white phosphorus. Its production range is based on the synthesis of carbide from chalk and coke in an electric furnace, which consumes large amounts of electricity. Currently there is only limited production of pesticides. The plant in Piesteritz emitted enormous amounts of dust, sulfur dioxide and nitrogen oxides into the air in 1989. The processes used generate cyanides and hydrogen cyanide, which are then processed further. There is no treatment plant for the waste water on the premises. Random water samples contained large amounts of cyanide in addition to slightly elevated concentrations of phosphate, benzene, toluene, dichloro- and pentachlorobenzene and also the heavy metal, copper. Plant management was very open to discussion and elucidated the origins of some of the pollutants but expressed doubts about other pollutants found by Greenpeace in the waste water, for example, the organochlorine compounds, which were neither used nor produced in the plant. The concentrations of some of the chlorobenzenes in particular were markedly elevated although the cause for this could not be clearly identified. Prospects A number of pollution control measures have been planned and financing for others is being sought. The plant management hopes that pollution of the Elbe with the plant's waste water will be abated by 1995 when the Wittenberg/Piesteritz combined sewage treatment plant will be completed. Although construction of a combined sewage treatment plant for industrial and municipal waste is not without problems, any problems arising should basically be solvable by pretreatment of individual streams of the industrial waste water in the chemicals plant. It is, however, uncertain whether an ecological overhaul of the carbide production process is feasible and, given the product range, even sensible. The Mulde With the confluence of the Mulde near Roblau the quality of the Elbe water suddenly deteriorates. The Mulde adds water with low oxygen content and a high organic load (up to 19 milligram BOD/5 days and up to 100 milligrams COD/Cr) to the river. This reduces the oxygen concentration in the Elbe to less than 2 milligrams per liter and produces a rapid increase in the nitrogen concentration. Furthermore, the concentration of salt and heavy metals, in particular mercury, increases. The main polluters of the Mulde are the industrial plants in the Bitterfeld-Wolfen area. VEB Chemiekoubinat Bitterfeld (Bitterfeld State-Owned Chemicals Combine) The Halle region with the VEB Chemiekombinat Bitterfeld (CKB), the Wolfen Film Factory and other companies is known worldwide as an ecological disaster area. Here six thousand smoke stacks emit hazardous substances into the environment, but only 675 of them are registered with the authorities as emitters and are monitored by regulatory agencies. Chlorine is found at the center of CKB production processes. It is inevitably formed as the coupling product of chloralkali electrolysis during production of potassium or sodium hydroxide solution. The chlorine is reacted further to chlorinated solvents and chlorofluorocarbons (CFC's, CFC-11, CFC-22) and used, for example, in the production of phosphorus chlorides, chlorobenzenes, chlorophenols, pesticides, organic dyes, silicones, etc. Measurements The biggest problem in the 200,000 cubic meters of waste water per day is mercury. The chloralkali electrolyses lose five tons every year, which is a quarter of the mercury load discharged into the North Sea by the Elbe every year. Hidden behind such collective terms as "dissolved organic carbon" or "chlorinated hydrocarbons" were often many highly toxic pollutants, as analysis in the Beluga's laboratory revealed, including the trimethylester of dithiophosphoric acid (possibly from pesticide production), 2,4,6-trichlorophenol, chloronitrobenzenes and chlorinated ethanes. Beginnings of a cleanup? The damage to the environment caused by the Chemiekombinat Bitterfeld is so grave that it will take decades to repair. A convincing concept for pollution abatement understandably enough does not exist as yet. The only immediate action to date has been the shutdown of a few production processes. Further planning leaves much to be desired. Instead of phasing out chlorine production because of the ecological risks, plans are being made to install a chlor-alkali electrolysis according to the membrane process that operates without mercury emissions. CFC-11 and CFC-12 production is to be replaced by the production of CFC-22, which is also an ozone-depleter but still permitted as a "substitute". VEB Fotochemisches Kombinat Wolfen (Wolfen State-Owned Photochemicals Combine) The Photochemicals Combine with a total of 21,000 employees produces magnetic tapes, films, photographic papers and photo chemicals as well as viscose fibers and cellulose. Every day 125,000 cubic meters of waste water with an enormously high concentration of oxygen-depleting substances are discharged. At almost 4,200 milligrams of COD the waste water samples taken by Greenpeace contained the second highest load of the entire trip. A total cleanup of this disastrously polluted waste water is no where near in sight. Although isolated shutdowns will undoubtedly bring considerable reductions, the film factory in Wolfen will not have its own neutralization and sedimentation plant until 1998. In addition to a very high COD value, Greenpeace determined extremely high loads of chlorobenzenes and phosphate as well as elevated levels of heavy metals. Prospects Viscose fiber production already ceased in December 1989 and sulfate wood pulp production was discontinued in the summer of 1990. Production of sulfite wood pulp will cease in January 1991. Chlorine bleaching will be totally eliminated from future wood pulp production. Films and magnetic tapes are to be produced in the future jointly with Agfa-Gevaert AG, a Bayer subsidiary. The Silbersee (Silver Lake) The "Silver Lake" is an environmental scandal without precedence. It is a strip mining pit that has not been sealed and that is presumably in contact with the groundwater. This pit serves literally as the sedimentation basin for untreated water from pulp and viscose production in Wolfen before it flows into the Spittel and subsequently the Mulde. It is an eerie sight: a lake full of foam with dark brown water and shores lined only with dead trees - it could well be a lunar landscape. Since chlorine bleaching is used in Wolfen, it seemed reasonable to assume that deposits in the sludge of the pit included dioxins and other chlorinated hydrocarbons. Therefore, Greenpeace took a sludge sample and had it analyzed: At 25 to 70 nanograms of dioxin (expressed as the toxicity equivalent, TE) per kilogram dry substance, the sludge does contain increased amounts of dioxin but not of the order that would alone require an immediate cleanup. The same is true for the chlorobenzenes and chlorophenols. Nevertheless, these loads must certainly be taken seriously. The heavy metal content (zinc, lead, arsenic, cadmium, chromium, copper, nickel and mercury) of the "Silver Lake", however, currently calls to mind that of a coal mine and should be immediately eliminated. The measures taken thus far to limit damage to the environment are inadequate and a comprehensive abatement program is urgently needed. The Saale With its confluence with the Elbe near Barby the Saale inflicts another blow to the already ailing main stream. Its contribution to oxygen-depleting substances alone accounts for 4.9 per cent of the total load of the Elbe measured at Schnackenburg. Added to this are large amounts of nutrients, salts, cyanides, heavy metals, phenols and chlorinated hydrocarbons, in short, once again the whole horror of chemical water pollution from A to Z. Four large groups of polluters are chiefly responsible: the potassium industry, metals mining and smelting, brown coal processing and the chemicals industry. Other polluters include the pulp industry in Blankenstein and Merseburg, as well as the Synthetic Fiber Combine in Schwarz on the Wipper but also municipal sewage and runoff from surfaces used for agriculture. In a random sample taken from the Saale, Greenpeace found the highest river concentration of dichlorobenzene (106 micrograms per liter) and almost 1000 micrograms of phosphate per liter of Saale water, which is twice as high as the phosphate content of the Elbe above the confluence of the Saale. Low temperature carbonization of brown coal High environmental loads originate from the low temperature carbonization of brown coal in Bohlen and Espenhain. The waste water there is highly polluted with phenols as well as other hazardous substances. However, the air pollution from dust, suIfur dioxide, hydrogen sulfide, mercaptans, tar and other hazardous substances is probably even worse. Abating this pollution would be so costly that shutdowns are planned instead. VEB Chemische Werke Buna, Schkopau (Buna State-Owned Chemical Works in Schkopau) The Buna Chemical Works in Schkopau is one of the largest producers of chemicals in the territory of the former GDR and the largest producer of polymers ("plastics and elastomers"). The combine has over 20,000 employees. Buna has engaged in large-scale production of the polymer PVC since 1938. PVC is formed by polymerization of the carginogen, vinyl chloride. The carbide synthesis carried out at Buna is detrimental in a number of ways: For every ton of product synthesized up to three tons of chalk sludge are generated as toxic waste. In addition, the massive air emissions (eg dust) and the waste water (cyanides, etc.) really require purification, which is costly and has never been carried out. At the same time just one of the twelve carbide furnaces in Buna consumes as much energy in one hour as the city of Leipzig in one day. Plant emissions Dust and sulfur dioxide emissions constitute the major air pollutants. Nitrogen oxides contribute to pollution in amounts that are almost as high. Large amounts of pollutants are also discharged into the Saale with waste water (230,000 cubic meters daily), including the extremely toxic heavy metal, mercury, of which over 20 kilograms is discharged daily into the Saale. It emanates on both from chlor-alkali electrolysis facilities and from acetaldehyde production. Workers cannot be employed there for more than four weeks; afterwards they are so highly contaminated with mercury that they must be transferred to another job location. Other problem substances in the Buna waste water are cyanide, ammonium salts, oxygen-destroying substances, surfactants, volatile and chlorinated hydrocarbons. Ever since part of the carbide production with its high water demand has ceased, all of the waste water can be disposed of via the treatment plant, which has improved the situation. The shutdowns have also led to a decrease in the mercury load in the waste water from more than 20 kilograms daily to 7 kilograms. In the future surfactant recycling and an expansion of the biological treatment plant should provide further improvements. Planned restructuring In the next few years the Buna Chemical Works plans to completely cease carbide production. It is hoped that this will produce a substantial reduction in emissions and toxic wastes. Carbide substitution is already in full progress. Due to the high energy savings production costs could even be lower than they were before substitution. In the next few years the synthesis of the starting materials will be redesigned on the basis of clean petrochemical processes. Most of the Mercury emissions have been abated, as both the acetaldehyde production (effective October 31, 1990) and the in- house chlorine production have been discontinued. The chlorine required by the plant is now purchased from the USSR. Further abatement of pollution around Buna should be achieved through construction of a power plant fired by hard coal. It is currently unclear what role chlorine chemistry will play in the plans of Buna's management. After the opening of the former GDR the Buna Works started to work closely with Huls AG of the former FRG, which has its own production of chlorine, PVC and other chlorinated hydrocarbons. Huls AG could be planning to move production processes encountering difficulties in the western part of Germany. VEB Leuna-Werke "Walter Ulbricht" ("Walter Ulbricht" State-Owned Works in Leuna) The Leuna Works has almost 30,000 employees (1988). Like the Buna Works, it has a wide product range. However, crude petroleum constitutes the basis of the product range at Leuna. The former BASF subsidiary has been operating a plant for the synthesis of ammonia from atmospheric nitrogen since 1916. The plant is a considerable nuisance to its surroundings, for example, due to the permanent odor of diesel oil and phenol. Greenpeace found massive pollutant concentrations in preliminary samples of waste water from the Leuna Works taken- in March 1990. The amounts of chlorinated hydrocarbons (AOX), solvents, the heavy metal, nickel, as well as pesticides, which were found repeatedly, were particularly high. The enormous amounts of waste water discharged by the Leuna Works contribute substantially to the total load of the Saale and thus also of the Elbe. The nitrogen discharge is higher than in any of the other sections of the Elbe, including even discharges emanating from the Piesteritz agrochemical works. The Leuna Works is also one of the biggest emitters of oxygen depleting substances: their contribution to the total pollution of the Elbe at the former border community of Schnackenburg was estimated at four per cent! Other pollutants in the Leuna waste water are phenols, hardening constituents, sulfite, extractable substances, surfactants and cyanides. Future plans First steps to reduce the waste water load are in the planning stage and should be completed by 1993. To avert bankruptcy the Leuna management board is currently (September 1990) working on a new company plan that is to ensure a "ecologically safe and competitive company that will endure". VEB Fahlberg-List, Magdeburg The largest pesticide plant in the territory of the former GDR with about 2,000 employees is located in Salbke, a district of Magdeburg, on the left bank of the Elbe. A wide variety of agricultural chemicals in addition to sulfuric acid and pharmaceutical products are produced here. Belonging to the group of agricultural chemicals are fertilizers (super phosphate) and pesticides, including insecticides, herbicides, fungicides and caustics. Of these the mercury containing caustic ("Falisan") and the organochlorine pesticides (eg "Melipax") are especially problematical. Not only their production but also their usage is detrimental to the environment and health, as they are hardly degradable. Other products include preparations, such as the sweetener, saccharine, the disinfectant, chloramine T, ephedrine, the cough medicine, bromhexin (based on bromobenzene) and various barbiturates. Large amounts of raw materials and products are stored on the plant's premises. Production residues are also stored in drums on concrete surfaces in the open. An inventory list of substances contains over 2,000 individual substances. Pollution from the plant Every hour the VEB Fahlberg-List discharges 500 cubic meters of waste water into the Elbe. Preliminary random samples of the waste water contained substantial amounts of hazardous substances but primarily mercury and organic pollutants. There were dangerously high concentrations of the aromatic compounds, benzene, toluene and xylene as well as numerous chlorobenzenes (including hexachlorobenzenel) and chlorophenols, chlorinated solvents and pesticides. During the Elbe trip these findings were confirmed by the ship's laboratory, which identified other hazardous substances as well. Moreover, the grounds were permeated by an intense odor and dust emanating from the highly toxic pesticides and the super phosphate fertilizers. After the sewage pipe had been sealed by Greenpeace the production manager ceased all production. Current production accounted for most of the pollutant effluents. Only production of lindane and the related compounds, alpha- and beta-HCH had already been stopped in 1981. The fact that these substances could still be detected in the waste water indicates that the soil is highly contaminated with these substances! Talks with the plant management revealed that the plant planned to cease production of the caustic, phenylmercury, and the chlorine pesticides. Prospects The most significant achievement of the Greenpeace campaign was to make public the pollution of the plant's waste water. In addition the pollutants in the waste water were analyzed for the first time. Several immediate steps were also taken to abate pollution of the Elbe: discontinuation of some production processes (Falisan, Melipax, sulfochlorination) and production cutbacks (ephedrine) together with the installation of equipment for collecting distillation residues containing pollutants has improved the quality of the waste water. Thus benzene emissions have been reduced by about 80 per cent and the mercury emissions totally eliminated. Immediate cessation of the synthesis of especially hazardous substances, such as mercury caustics and chlorine pesticides, is essential. For other plant areas it is a matter of determining what can be done to ensure that future production will not be detrimental to human health and the environment. In the process it will be important to integrate measures to minimize pollutant emissions in each individual process and not to rely on end-of- pipe technologies, such as central waste water treatment or filtration plants. This is a demand that the responsible water conservation authority has been making for years. VEB GroBgaserei Magdeburg (Magedeburg State-Owned Gasworks) The Magdeburg Gasworks is the second largest town gas producer of the former GDR and together with the coking plant in Zwickau supplies over one-third of the blast furnace coke requirement of the former GDR (altogether 2.5 million tons per year). Environmental pollution The Magdeburg Gasworks discharges 700 cubic meters of waste water into the Elbe daily. It is only purified by a gravity phase separation which, however, fails to retain a large proportion of hazardous substances. True purification stages, such as a biological treatment of waste water, do not exist. In the random samples of waste water dramatically high concentrations of cyanides (250 milligram per liter), benzene (18 milligrams per liter), toluene and xylene as well as polycyclic aromatic compounds (16 milligrams per liter) were measured. The plant pollutes not only the Elbe but also the air to an intolerable extent. The ancient furnace batteries leak and permit carbon dioxide to escape in concentrations significantly higher than the maximum allowable concentrations. Moreover, the workers are presumably exposed to aromatic compounds like benzene, toluene and xylenes as well as to polycyclic aromatic compounds, aromatic a mines and other carcinogenic substances. The plant management frankly admitted to Greenpeace that the plant is one of the major polluters of the Elbe. Until at least the middle of last March emissions far surpassing the tolerable limits were the "order of the day", as revealed by studies by the Magdeburg Water Conservation Agency. Prospects In 1991 construction of a sewage treatment plant will commence and it is supposed to be completed by 1994. The Elbe will be spared 4,900 tons of nitrogen, 435 tons of phenols and 22 tons of cyanide every year. A method for wet desulfurization is also planned as another pilot project. Immediate replacement of the furnace batteries is essential for reasons of industrial safety alone (just to protect the employees), as the Magdeburg gas works will continue to be in operation until conversion to natural gas which will probably only take place several years from now. VEB Zellatoff- und Zellwolle-Werke Wittenberge (Wittenberge State-Owned Cellulose and Viscose Works) The plant previously produced sulfate wood pulp, viscose fibers, regenerated cellulose films, spun rayon, cellulose acetate membranes and tall oil products. The equipment used for these processes are "extremely worn". Consequently, an exceptionally high hazard to the air and water emanates from the plant. Thus the bleaching plant waste water is a significant source of organochlorine compounds including even dioxins. Random samples of the waste water showed high values for AOX, COD and chloroform. Moreover, various chlorophenols and chlorobenzenes (including also hexachlorobenzene!) as well as elevated zinc values were found. Because of overdue modernizations, the plant has cut back its viscose production and discontinued production of regenerated cellulose films and chlorine bleaching. The plan to combine treatment of the industrial waste water with the municipal sewage of Perleberg should be viewed with skepticism. Usually the resulting purification does not reach the level attainable with a separate treatment of industrial waste water and sewage. In the future the Wittenberge cellulose plant plans to change over to the so-called ASAM process. This process permits chlorine-free bleaching. Hamburg's contribution to pollution of the Elbe Eleven per cent of all the inhabitants (three million) of the entire drainage area of the Elbe live in the region from Schnackenburg to Cuxhaven. Approximately half of these (5.5 per cents live in Hamburg. The Hansa city makes a disproportionately high contribution to pollution of the Elbe. Thus according to the Emissions Land Register of 1986 the city of Hamburg discharges into the Elbe, relative to the preload, 3 per cent COD, 6 percent BOD (over 5 days), 12 per cent ammonium salts, 21 per cent orthophosphate, 6 per cent copper, 3 per cent cadmium, 3 per cent lead and 0.3 per cent arsenic. For the navigable waters there are 1,100 water permits regulating about 3,000 discharge locations. Added to this are widespread discharge locations that are not or cannot be registered and whose numbers can only be estimated. A brief description of some of the major polluters follows: Norddeutsche Affinerie AG (North German Refinery) The Norddeutsche Affinerie (NA) is one of the largest nonferrous metallurgical plants and the largest copper mill in Europe. Recently the NA has also begun smelting of computer and electronic scrap. It is Hamburgs biggest industrial discharger of heavy metals. Although it has never had a discharge permit for chlorinated hydrocarbons (CHC) the surrounding water sediments show one of the highest CHC waste loads. The concentrations of hexachlorobenzene (HCB) and the pesticide DDT are the highest in the Hamburg harbor. Lubricating oil industry and oil refineries. A major portion (34%) of the approximately 3,000 hectares of land comprising the Harburg harbor is used by the basic materials processing and oil refining industries. In 1983 73 per cent of the 184 million cubic meters of cooling and waste water was discharged into surface waters or the subsoil. Aside from the sewage plants, the oil refineries were the biggest direct discharger of ammonium salts (Shell: 4.5 per cent, Holborn: 2.4 per cent) until at least 1986. The DEA (previously Texaco), at 1,100 tons in 1986 (7.1 per cent), was Hamburgs biggest industrial direct discharger of chlorinated hydrocarbons (AOX). Sewage treatment plants. The dense population produces a large amount of municipal sewage from households, small and medium-sized businesses and the industry, which is carried with rain water primarily to the huge Kohlbrandhoft/Dradenau sewage treatment plant. Despite reduction of the pollutant load in the treatment plant, the discharged treated water still constitutes a heavy load for the Elbe. In 1988 600 tons of ammonium salts, 3,600 tons of total nitrogen and 400 tons of phosphorus were discharged into the Elbe by the Kohlbrandhoft/Dradenau plant. Furthermore, in the random waste water samples a high benzene concentration was found which is presumably attributable to inadequate pretreated of industrial effluents. Shipping. Shipping pollutes the river with sand blasting and paint residues or oil-containing (bilge) water among other things. However, the extent of contamination is very difficult to quantify. Moreover, the navigable channel is deepened regularly by dredgers and mud harrows. With dredging the dredged materials are pumped onto fields and the water running off is loaded with exceptionally high amounts of pollutants. With a mud harrow hazardous substances that have deposited in the inner harbor are swirled up and partly remobilized. This leads to a high local contamination of the river with toxic substances. The source of pollutants in the sediment cannot always be identified unequivocally. Comparison of river samples with reference samples having pollutant profiles specific to certain processes can indicate a possible emitter. With this method it can be clearly shown that many pollutants in the sediment are abandoned pollutant wastes that have been produced locally and do not emanate from the area of the former GDR. DOW Stade GmbH, Butzfleth. The Dow Stade plant on the Butzflether Sand was founded in 1969 as part of an industrial complex that also includes a nuclear power plant and an aluminum mill. Any Dow production process starts with oil and chlorine. Dow is the biggest chlorine producer in the FRG. The approved capacity is 1.25 million tons, of which approximately 1 million are utilized. The plant is totally dependent on chlorine: not one of Dow's production units could be operated without chlorine (or secondary products of chlorine) as it is currently installed. In the random waste water sample the highest nickel concentration of the entire trip was measured. In addition, the concentrations of 1,1,1-trichloroethane and pentachlorophenol were remarkably high. However, the campaign at Dow Stade was not directed at these pollutants but at the products themselves. These include, for instance, chlorinated solvents, which on the one hand cause long-term damage to organisms and on the other hand, like the CFC's, contribute to destruction of the stratospheric ozone layer. The production capacity for perchloroethylene and trichloroethane alone exceed 200,000 tons. With the first use of these compounds roughly 50 per cent evaporate directly into the atmosphere. At 10 tons per year (according to Dow's data), the solvent emissions in the waste water are comparatively small. Chemical pollution cannot be combatted here by a reduction in waste water loads but only by banning the use of chlorinated solvents. Another serious problem is the risk of contamination of products with ultra toxic substances from these production processes, such as dioxins and hexachlorobenzene. The danger emanating from this could be at least equal to that from direct plant emissions. Prospects. Like many other chemical companies, in past years Dow Stade GmbH has at least to a large degree met the demands of the environmental movement "for closed production cycles". These technical emission reductions are counteracted by massive emissions of problem substances and carried-over ultra toxic substances from products when they are used as well as when they are discarded. This represents an irresponsible threat to the environment and human health. Temming AG. The Temming AG in Gluckstadt on the lower Elbe produces graphical papers, packing paper, recycling papers from waste paper, but also cellulose from cotton tinters for further chemical processing. Cellulose production from linters is a big source of pollution because of chlorine bleaching. Temming discharges 25 kilograms of organochlorine compounds from cellulose production into the Elbe daily. In the random sample an AOX of 1,100 milligrams per liter was determined. The COD was 385 milligrams per liter. Prospects. Construction of an anaerobic waste water treatment plant should reduce the COD. In addition, the planned conversion to bleaching with chlorine dioxide will result in a reduction in AOX. However, this conversion will not prevent organochlorine compounds from continuing to enter the Elbe. Incineration of the pulp liquor should also continue to pose a dioxin threat. Moreover, Temming plans to expand its tinters production so that part of the AOX saving would be counteracted by increased production. The intended reduction of AOX does not go far enough. The goal must be an AOX value of zero, which can only be achieved by a complete phase-out of chlorine chemicals from the bleaching process. BAYER AG, Brunsbuttel. BAYER Brunsbuttel is the newest West German plant of the Bayer group. After the state of Schleswig-Holstein had made numerous concessions for a new industrial development area on the Elbe, the plant started production in 1977. To date BAYER has set up facilities for the production of the polyurethane basic materials, MDI and TID, dye intermediates (the letter acids), over 100 different organic dyes (azo dyes), the pesticide intermediate, methylethylaniline, and Vulcanox 20/40, an antioxidant for rubber. Bayer also operates a plant for incineration of toxic, aqueous wastes from its own plant, PGB- containing oils from the mining industry in Nordrhein-Westfalen (North Rhine-Westphalia) as well as a variety of other liquid toxic wastes from ali parts of the former FRG. Facilities for producing aniline and iron oxide pigments are planned or under construction. In the preliminary random waste water samples Greenpeace found, in addition to copper and nickel, also 1.2 milligrams of hexachlorobenzene per liter, a particularly hazardous toxic substance with a long lifetime in the environment. The BAYER products are manufactured from extremely hazardous substances like chlorine and phosgene. This results in a permanent threat to workers and the populace in case of an accident. The polymer, polyurethane, is one example: Polyurethane is formed by reaction of TDI (tolylene di-isocyanate) or MDI (diphenylmethane di-isocyanate) with polyhydric alcohols. BAYER produces only one of the two reaction components, TDI or MDI. MDI and TDI are toxic and allergenic. TDI in particular is already hazardous to health in concentrations below the threshold odor. Since MDI and TDI are often processed further in smaller factories and shops that do not have adequate safety equipment, this property is especially problematical. Polyurethanes are relatively safe as finished plastics. However, numerous toxic additives or additives that are detrimental to the environment are used in the "composition" of the finished synthetic products. For example, ozone depleting CFC's are used for the production of insulating foams and flame retardants in building materials. In 1986 about 17 to 25 per cent of the total CFC's consumed in the FRG was used in polyurethane foams. Drinking water. The drinking water situation in the territory of the former GDR presents the following picture: The water supply in the drainage area of the Elbe is practically exhausted. The river's water is sometimes used more than ten times. Because of the lack of sewage treatment techniques and the pollutant intensive production facilities on the Elbe the drinking water of the Elbe communities is often more apt to be inadequately diluted waste water than a healthy nourishment. The measurements carried out by Greenpeace in March 1990 at seven water works on the Elbe clearly demonstrate that the pollutants from industry and agriculture discharged into the Elbe eventually end up, for instance, in Dresden's drinking water. The contamination of the drinking water with chemicals is actually increased by disinfection of the water with chlorine. The emission limits of the Drinking Water Regulations for chlorinated solvents are almost exhausted the pure water of two water works. It is likely that the emission limits are regularly surpassed. For instance, in Tolkewitz. Saloppe and Brockwitz water works in the in the Dresden/Meiben area chloroform concentrations of more than 100 milligrams per liter were measured. Playing down the situation and exhausting emission limits stand in the way of a medium-term improvement in the drinking water situation. The installation of a long-distance water supply system will only shift the problems to another time and place. Evaluation and conclusions As devastating as the conditions found by the Beluga at a number of companies in the former GDR may be, the trip revealed that there is one area where they have been far ahead of the FRG since the Fall of '89. This is in the exemplary willingness of many of those in responsible positions to provide information and to talk openly about company problems. In comparison, the (old) Federal Republic could almost be called a developing country. Data on the types and amount of materials produced and marketed as well as on emissions are still being held back with the excuse that they are company secrets. The chemicals industry is still bitterly defending its information monopoly. Considerations of how to clean up the Elbe often include a glance at the Rhine where progress has unquestionably been made in the past 15 years. However, pollution abatement is stagnating and past results are by no means sufficient. The concentrations of some heavy metals in the Rhine have even increased significantly in the past few years. And: Reduced concentrations of heavy metals and other long-lived hazardous substances do not necessarily represent an improvement but only a slower deterioration of the state of the environment. The Rhine with its pollutant load is still the biggest single source of pollution of the North Sea, whose condition is continuing to deteriorate despite a certain degree of success in cleaning up the Rhine. Problematic production processes have only actually been discontinued in rare cases. Usually a decrease in the direct load of the river with hazardous substances is achieved by accepting an increase in indirect loads in the form of trash, widespread emissions or pollution from the products and their usage. From our point of view the road taken here is extremely unsatisfactory and West German politicians and industrialists have absolutely no right to pat each other on the back. The long-standing criticism of the way the West has been exploiting nature and health is still valid despite the dramatic conditions in the former GDR. Making the GDR into a mere copy of the former FRG, as industry and government are trying their best to do, will also mean taking on all the mistakes of the West. The economic system of the West is characterized by large scale production of short-lived (ie intended for consumption and not for use) goods accompanied by a wide product range. Almost none of the sources of materials and energy exploited are renewable (natural resources such as ores and oil). A constantly increasing number and amount of synthetic substances are being produced and marketed. Their behaviour and impact are largely unknown, for the most part uncontrollable and not necessarily identifiable. This economic process gives rise to huge amounts of refuse (these are residual substances and emissions from production and every product after use). In other words, nothing but refuse is produced, although some of it can be used for a limited time period. This means, however, that all substances involved in this process will sooner or later end up in the soil, air or water. Sometimes their odysee takes them through plants, animals and humans. The consequences of this type of economics are not all known. We know that some of these substances destroy our basis for life because they cause irreversible changes in our environment or disturb the balance of natural systems. We do not know what new equilibria will look like (for example has the atmosphere-ocean-biosphere system, which determines our climate, departed from equilibrium with man's assistance?) and what species will still will be able to exist under the new equilibrium conditions. Technical pollution control measures (for example, filters, sewage treatment plants or plants that exploit energy more efficiently) are important but by no means sufficient. Such measures, as they have been increasingly instituted in the Federal Republic of Germany in the past two decades, have not been able to abate continued destruction of our basis for life. They are only "end-of-the-pipe" measures starting at the end of a detrimental process, not at the beginning. Often their effects are negated by the higher goal of "growth". (For example, the sharply increasing number of cars has increased the emission of air pollutants despite introduction of the catalyst.) Man is a part of nature and is subject to its laws as are all living beings. We should learn from nature where reliable survival techniques have existed for ages. Every production process, every conversion of materials consumes energy that must first be generated. Its generation and usage is usually associated with pollution (this applies especially to non-renewable sources of energy: thus emission of CO2 from combustion of coal and oil enhances the so-called "greenhouse effect"). The large amounts of substances that we use in our economic processes cause environmental problems not only during production but even more so after the products have been put on the market. This is particularly true if these are heavy metals or synthetic substances, such as chlorinated hydrocarbons (CH). The conversion of materials and energy consumption must therefore be minimized. The question, "Can we afford a new car (walkman, TV, etc.) every few years?", should not be a matter of the current retail price. From procurement of raw materials through production of the product until fate of the product materials after use, it all has to be taken into account and the overall ecological balance drawn up. Whoever does this will come to the conclusion that the car, like so many other goods, has such a "cheap" sales price only because we produce, use and discard it at cost to the environment (ie today's living community and future generations). The question just asked could probably sooner be worded: Can the human race afford to buy a new car (walkman, TV, etc.) every few years? We have to learn to think through the processes associated with our lifestyle from beginning to end and ask ourselves whether we can or want to expect for ourselves or others a certain product, type of production or lifestyle. The assertion repeatedly made that products are put on the market to meet the needs of the consumers misrepresents the facts. Today a market is first created for a majority of products. Then the consumer is made to believe he needs the product. An entire branch of industry, the advertising industry, makes its money creating markets for products that are really not needed. The environmental problems associated with the product are not mentioned. It is impossible to ask about the "adverse effects" of a product even after damage has been done. The freedom of companies to decide what product to produce and how to produce and distribute it places the burden resulting from the adverse effects of these creations on the general public. Instead there should be public discussion on what should be produced and how. Only then will society be capable of handling the ecological challenge of the future. However, the basis for any wide discussion is free access to information. In the past manufacturing and industrial groups have not always had the best reputation in this respect. The myth of the industrial secret has even been successfully used in court up to now with the consequence that the consumer, environmental groups, scientific institutions and government regulatory agencies have been forced to grope in the dark while the environment was being ruined. This must be stopped. What does all this have to do with the Elbe, the interested reader might now ask. Our answer is: Everything! The Elbe is suffering, like many other ecosystems, from the effects of our lifestyle. The questions arising from the impact of our economic system and lifestyle on our environment and future generations must be discussed and decisions made on a wide political basis. Science can be a useful aid in this process but should be seen by politicians and society as a convenient "final authority". Furthermore, these questions may never be decided by the industry "for all of us" exclusively on the basis of sales and power. To be concrete - what positive goals must be pursued to improve the current state of the Elbe and the rest of nature: 1. A conversion of our economy to renewable resources. In the territory of the former GDR a conversion from brown coal to oil as the source of energy and raw materials is currently taking place. A superficial comparison of the two resources shows oil to be more favorable both ecologically as well as economically. However, converting chemical production to an oil basis cannot be the only long-term goal of an ecological redevelopment policy. This only pushes a number of problems out of sight. Basic trends of current industrial production, which consumes large amounts of raw materials and energy, in the direction of a global ecological catastrophe are not even being considered: * destruction of the environment through depletion of the reserves in oil-producing countries and the oceans * use of very distant resources instead of local resources, therefore permanent loading of the environment through losses during transport, storage and handling as well as through accidents (see the Exxon Valdez tanker accident) * dependence of the entire economy on the world market for oil * the greenhouse effect. 2. Traffic reduction and promotion of public transportation for passengers and goods and the use of bicycles The automobile is today one of the biggest sources of environmental pollution. Air traffic inflicts heavy damage on the earth's atmospheres We will have to give consideration to how much mobility we can afford in view of the costs to the environment and future generations. 3. Attempt to achieve maximum recycling Once the economy has been converted to maximum use of renewable resources achieving a maximum recycling of nonrenewable natural resources still needed in small amounts will be essential. However, recycling "per se" does not necessarily make a positive contribution to the environment. The question to ask is, what is being recycled to what. (The production of park benches and flower pots from used PVC window frames does not deserve to be called recycling!). 4. Products and technologies must be designed to be repairable. This should apply both to the products and technologies themselves and to any possible negative effects they might have. To reduce consumption of raw materials and energy, products should be designed to be long-lived, ie repairable. The products themselves often emit the highest amounts of pollutants into the environment. They act as widespread sources of pollutants and their impact is usually irreparable, especially if they are virtually non degradable and are bioaccumulable. (Examples: many applications of halogenated hydrocarbons, such as polymers and polymer additives, solvents, pesticides or flame retardants). 5. Development of an ecologically oriented chemicals policy The chemicals producers should not be granted freedom to produce or convert chemicals as they wish. Likewise, instead of presuming the innocence of new chemicals proof of their safety must be compulsory. The idea of prevention must be translated into real action not just in colored brochures but as a central policy of the chemicals industry. 6. Ecological land cultivation To prevent loading of ground and surface waters with nutrients, fertilizing should be restricted to those amounts that can be taken up again by plants from the soil. To date, immense damage has been caused by pesticides, whose expressed goal is to interfere with natural systems to destroy them. Contrary to claims by pesticide producers, restricting the duration and spread of pesticide effects is still an unsolved problem. Bioaccumulable and persistent pesticides must be totally banned. Instead other methods of plant protection like integrated land cultivation, biological plant protection, etc. should be introduced. 7. Decentralized technologies instead of high-risk large-scale industrial technology This applies both to the generation of energy and raw materials and to industrial production. 8. Freedom of information The right to information about the exploitation of natural resources is a fundamental right! This is the only way the public will be able to openly discuss chemicals policy and trends in economic development. 9. Critical production processes must not be transferred to the former GDR! Encouraged by high unemployment and the previously high pollution level in the states of the former GDR, many companies expect less resistance to critical production facilities there than in the former FRG (eg chlorine production, chlorine chemicals, waste disposal plants, combustion of computer scrap). 10. Establishment of funds for abandoned pollutant wastes Eastern and western Germany still have no solution to the problem of abandoned pollutant wastes. Here the industry must be forced to take action, for instance by establishing funds for abandoned polluted wastes similar to those that have already existed for years in the USA. It is self-evident that government support of these measures in every way possible (eg by legislation, official procurements or financing of research) is extremely important. Experience has shown that only massive public pressure and a lively discussion about future chemicals and economical and environmental policies can set things in motion that are needed to make the environment a better place to live. Used Literature (list omitted here; virtually all of it is German and unscannable)